Porous
media with directional water-transport capability have great
applications in oil–water separation, moisture-harvesting,
microfluidics, and moisture-management textiles. However, the previous
directional water-transport materials chiefly work in the air. The
materials with directional water-transport capability in the oil phase
have been less reported. Here, we fabricated a novel Janus fabric
with amphibious directional water-transport capability that can work
both in the air and oil phases. It was prepared using dip coating
and spraying to develop an oleophobic-hydrophobic to oleophobic-hydrophilic
gradient across the thickness of the fabric substrate. The fabric
allowed water droplets to rapidly transport from the hydrophobic to
the hydrophilic side when the fabric was either in the air environment
or fully immersed in oil. However, it hindered water transport in
the opposite direction. More importantly, the fabric can overcome
gravity to capture water from oil. Such an air–oil amphibious
water-transport fabric showed excellent water collecting capability.
In oil, it does not require any prewetting or extra pressure to perform
directional water transport, which is vital for water–oil separation
and microfluidics. Such amphibious directional water-transport function
may be useful for the development of smart membranes and directional
liquid delivery.