The development of triboelectric nanogenerators (TENGs) that exhibit enhanced durability and performance is crucial for their practical usage. Incorporating 3D and shape memory nanocomposites into TENGs is a promising strategy to achieve this goal. In this study, the effect of various oxide nanoparticles (Al 2 O 3 , SiO 2 , and TiO 2 ) on the TENG's performance was evaluated, and Al 2 O 3 was found to have the most significant impact. Subsequently, a shape memory melamine foam−poly(vinyl alcohol)− Al 2 O 3 [SM(MF-PVA-Al 2 O 3 )] nanocomposite was synthesized to fabricate a durable and high-performing TENG. The SM(MF-PVA-Al 2 O 3 ) nanocomposite has the ability to recover deformations and shape changes through heating (at 70 °C for 15 min), which restores the TENG's performance to its initial value without any noticeable difference. This recovery can be repeated multiple times. The resulting TENG exhibited a high performance (1325.96 V and 7.71 μA) and power density (70.99 mW/cm 2 ) and was capable of powering 110 commercial LEDs. Therefore, the SM(MF-PVA-Al 2 O 3 ) nanocomposite is a suitable material for fabricating TENGs with practical applications that are both high-performance and durable.