Porous membranes with under-liquid dual superlyophobic
properties,
which are difficult to achieve because of a thermodynamic contradiction,
have attracted considerable interest in the field of switchable oil/water
separation. Herein, a bioinspired mesh membrane with alternating hydrophilic
and hydrophobic chemical patterns on its surface that endows it with
superamphiphilic and under-liquid dual superlyophobic properties is
fabricated by a simple liquidus modification process. The as-prepared
membrane possesses a combination of under-oil superhydrophobic and
under-water superoleophobic characteristics in the absence of external
stimuli. Moreover, it can effectively perform the on-demand separation
of various oil/water systems, including immiscible oil/water mixtures
and oil/water emulsions owing to its under-liquid dual superlyophobic
properties.