2018
DOI: 10.1016/j.apcata.2018.01.007
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Smart designing of metal-support interface for imperishable dry reforming catalyst

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Cited by 55 publications
(39 citation statements)
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“…They do not contain any peak attributable to crystalline NiO, confirming the intimate mixing between Ni and the oxide support. This is also demonstrated by the temperature program reduction profile of NiAl MIL that displays only one peak centered at a high temperature of about 830 °C (Table and Figure S1a) typical of the formation of the spinel NiAl 2 O 4 phase . The high and homogeneous Ni dispersion throughout the sample is visible as well from STEM‐HAADF and EDX elemental mappings that show the superimposed Ni and Al distributions on a representative NiAl MIL grain (Figure ).…”
Section: Resultsmentioning
confidence: 56%
See 1 more Smart Citation
“…They do not contain any peak attributable to crystalline NiO, confirming the intimate mixing between Ni and the oxide support. This is also demonstrated by the temperature program reduction profile of NiAl MIL that displays only one peak centered at a high temperature of about 830 °C (Table and Figure S1a) typical of the formation of the spinel NiAl 2 O 4 phase . The high and homogeneous Ni dispersion throughout the sample is visible as well from STEM‐HAADF and EDX elemental mappings that show the superimposed Ni and Al distributions on a representative NiAl MIL grain (Figure ).…”
Section: Resultsmentioning
confidence: 56%
“…This is also demonstrated by the temperature program reduction profile of NiAl MIL that displays only one peak centered at a high temperature of about 830°C (Table 1 and Figure S1a) typical of the formation of the spinel NiAl 2 O 4 phase. [53,54] The high and homogeneous Ni dispersion throughout the sample is visible as well from STEM-HAADF and EDX elemental mappings that show the superimposed Ni and Al distributions on a representative NiAl MIL grain (Figure 8). In order to evaluate the impact on the material properties of the adopted preparation procedure (i.e.…”
Section: Characteristics Of the Parent Mil-53 Activated Mil And Imprmentioning
confidence: 90%
“…[23][24][25] In addition, it has been evidenced that a fine-tuning and intensification of the interactions between Ni and support can induce better anticoke and anti-sintering performance of the catalysts. 26,27 The effect of interactions between the active metal and support, as a result of the formation of a solid solution, on the catalysts' performance during dry reforming reaction has been widely evaluated in literature. Excellent activity and stability have been reported by Hu for the NiO-MgO (or CoO-MgO) solid solution; 28 the carbon deposition is inhibited by the isolation effect of small nickel particles formed on the catalytic surface coupled with the surface basicity of MgO.…”
Section: Introductionmentioning
confidence: 99%
“…One of the most promising approaches to the reduction of ohmic resistance is the application of electrolyte thin films having a thickness of about 10-30 µm [6][7][8]. Due to technological issues involved in the manufacture of such thin films, their formation should be carried out on a porous supporting substrate (cathode [9][10][11], anode [12][13][14], metal interconnector [15][16][17]) in order to ensure the mechanical strength of the cell. For this reason, questions arise concerning the production technology of supporting substrates.…”
Section: Introductionmentioning
confidence: 99%