We investigate the diffraction conditions and associated formation of stopgaps for waves in crystals with different Bravais lattices. We identify a prominent stopgap in high-symmetry directions that occurs at a frequency below the ubiquitous first-order Bragg condition. This sub-Bragg diffraction condition is demonstrated by reflectance spectroscopy on two-dimensional photonic crystals with a centred rectangular lattice, revealing prominent diffraction peaks for both the sub-Bragg and first-order Bragg condition. These results have implications for wave propagation in 2 of the 5 two-dimensional Bravais lattices and 7 out of 14 three-dimensional Bravais lattices, such as centred rectangular, triangular, hexagonal and body-centred cubic.The propagation and scattering of waves such as light, phonons and electrons are strongly affected by the periodicity of the surrounding structure [1,2]. Frequency gaps called stopgaps, emerge for which waves cannot propagate inside crystals due to Bragg diffraction. Bragg diffraction is important for crystallography using X-ray diffraction [3] and neutron scattering [4]. Diffraction determines electronic conduction of semiconductors [1,2] and of graphene [5], and broad gaps are fundamental for acoustic properties of phononic crystals [6,7] and optical properties of photonic metamaterials [9, 10].Bragg diffraction is described in reciprocal space by the Von Laue condition − → Here m is an integer, λ is the wavelength inside the crystal, θ is the angle of incidence with the normal to the lattice planes, and d is the spacing between the lattice planes. A stopgap is also formed when Bragg diffraction occurs on multiple Bragg planes simultaneously, which is called multiple-Bragg diffraction [11], and is fundamental for bandgap formation [2,12,13]. Wave propagation in crystals is described along high-symmetry directions [1]. Multiple-Bragg diffraction has been recognized in highsymmetry directions at frequencies above the first-order simple Bragg diffraction condition: m = 1, λ = 2d orhas not yet been observed at frequencies below simple Bragg diffraction [14].In this Letter we show that for high-symmetry directions multiple-Bragg diffraction can occur at frequencies below the first order simple Bragg condition. As a demonstration we have investigated diffraction conditions for two-dimensional (2D) photonic crystals using reflectance spectroscopy. A broad stopgap is observed below the simple Bragg condition, depending on the symmetry of the lattice. Our findings are not limited to light propagation, but apply for wave propagation in general, and therefore we anticipate similar diffraction for electrons in graphene [5], and sound in phononic crystals [6,7].We have studied light propagation in 2D silicon photonic crystals [17]. Figure 1(a) shows a scanning electron microscope (SEM) image of one of these crystals from the top view. The centred rectangular unit cell has a long side a = 693 ± 10 nm and a short side c = 488 ± 11 nm. The pores have a radius of r = 155 ± 10 nm and are approxima...