2018
DOI: 10.1371/journal.pone.0205443
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Slip of fluid molecules on solid surfaces by surface diffusion

Abstract: The mechanism of fluid slip on a solid surface has been linked to surface diffusion, by which mobile adsorbed fluid molecules perform hops between adsorption sites. However, slip velocity arising from this surface hopping mechanism has been estimated to be significantly lower than that observed experimentally. In this paper, we propose a re-adsorption mechanism for fluid slip. Slip velocity predictions via this mechanism show the improved agreement with experimental measurements.

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Cited by 3 publications
(4 citation statements)
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References 20 publications
(31 reference statements)
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“…The same mechanism applies even for the surface diffusion of large organic molecules with a planar structure, for which a strong bond with the substrate was assumed, as reported for a perylene derivative on a semiconductor surface . A similar mechanism has been proposed for the lateral diffusion of solvent molecules in contact with the surface, which may secondarily affect the mobility of the adsorbed molecules. The other process observed for the aggregation of R123 dye molecules is interparticle diffusion . In this case, a dye molecule must acquire sufficient energy to not only get released from the original adsorption site but also to leave the particle completely.…”
Section: Discussionmentioning
confidence: 56%
See 1 more Smart Citation
“…The same mechanism applies even for the surface diffusion of large organic molecules with a planar structure, for which a strong bond with the substrate was assumed, as reported for a perylene derivative on a semiconductor surface . A similar mechanism has been proposed for the lateral diffusion of solvent molecules in contact with the surface, which may secondarily affect the mobility of the adsorbed molecules. The other process observed for the aggregation of R123 dye molecules is interparticle diffusion . In this case, a dye molecule must acquire sufficient energy to not only get released from the original adsorption site but also to leave the particle completely.…”
Section: Discussionmentioning
confidence: 56%
“…The same mechanism applies even for the surface diffusion of large organic molecules with a planar structure, for which a strong bond with the substrate was assumed, as reported for a perylene derivative on a semiconductor surface . A similar mechanism has been proposed for the lateral diffusion of solvent molecules in contact with the surface, which may secondarily affect the mobility of the adsorbed molecules.…”
Section: Discussionmentioning
confidence: 56%
“…With the recent rapid development of computational science and technology, microscopic simulation has become an effective tool for understanding the microscopic behavior of liquid-solid interaction, especially the interface velocity of liquid on a solid wall [29,30,31]. It is documented that the nanoscale flow behaviors are mainly dependent on surface roughness [32,33,34] and wettability [35,36], liquid properties [37], and shear rates [34,38,39].…”
Section: Introductionmentioning
confidence: 99%
“…Wan et al [41] studied the slip length of liquid flow through rough solid-liquid interfaces in a restrained space using perturbation expansion and the Dyadic Green function, and the results showed that the total slip length at a solid-liquid interface is proportional to the slip length arising from the chemical interaction. Shu et al [31] explored the slip mechanism of fluid on a solid surface in terms of surface diffusion and proposed a re-adsorption mechanism for interface velocity slip. The previous investigations confirmed that the solid wall properties highly affected the liquid flow behaviors at the interface.…”
Section: Introductionmentioning
confidence: 99%