Size dependence of luminescence decay process in CsPbBr3 nanocrystals

Abstract

Lead halide perovskite nanocrystals (NCs) have superior luminescence properties compared to classical semiconductor NCs and they are considered promising materials for next-generation emitters. In this work, we measured the size and temperature dependence of the luminescence decay curve in CsPbBr3 NCs. To reproduce the experimental results, a simple model including one and two-phonon transitions between the exciton fine structures is introduced. It is found that the temperature dependence of the decay rates in small NCs is better reproduced by the two-phonon model rather than by the one-phonon model. However, the one-phonon process becomes more important for large NCs as the bright-dark splitting decreases.