Abstract:Various covalently linked dimers (CLDs) and their structural isomers have attracted much attention as a potential material to improve the power conversion efficiencies of photovoltaic devices and OLEDs through singlet fission (SF). However, the effect of the molecular configuration on improving the efficiency through the spatial arrangement has not been explored yet. Here, we designed and synthesized two covalently ortho-linked pyrene (Py) dimers, anti- and syn-1,2-di(pyrenyl)benzene (Anti-DPyB and Syn-DPyB), … Show more
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