The development of new radar-absorbing structures (RASs) with strong microwave absorption, fine thickness and adequate structural performance is imperative. Herein, nanocrystalline Ni 0.5 Zn 0.5 Fe 2 O 4 was synthesised by a facile and effective sol-gel autocombustion technique. The structural and magnetic properties of ferrite were determined by various characterisation techniques, and E-glass/epoxy-based nanocomposites with different weight percentages of ferrite were fabricated by in-situ polymerisation. Further, electromagnetic properties were investigated to elucidate the possible absorption mechanism of the fabricated structures. The 4-mm-thick double-layered E-glass/epoxy/nickel-zinc ferrite composites exhibited reflection loss (RL) of <−10 dB for a bandwidth of 2.4 GHz and a maximum RL of −33 dB at 9.6 GHz. This performance was attributed to the larger magnetic loss and sufficient matching of electromagnetic parameters. This study provides a unique insight into the utilisation of Ni 0.5 Zn 0.5 Fe 2 O 4 for producing lightweight and relatively thin RASs in the X-band at a low cost.