Single Gas Permeation on γ-Alumina Ceramic Support

Kajama, Mohammed Nasir; Shehu, Habiba; Okon, Edidiong; Orakwe, Ify

doi:10.4172/2090-4568.1000154

Cited by 2 publications

References 7 publications

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Graphene-Coated Halloysite Nanoclay Membrane for the Enhanced Separation of Hydrogen from a Hydrogen–Helium Mixture

Dutta

Das

2022

ACS Appl. Mater. Interfaces

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This study highlights the separation of hydrogen from H2–He mixture gas by a graphene-coated halloysite nanoclay membrane. The graphene-coated clay membrane along with its pure clay counterpart is successfully developed and studied for gas separation using hydrogen (H2)–helium (He) single and mixture gases. Hydrothermal and nonhydrothermal methods were applied for the synthesis of a ″coated″ membrane on a porous alumina substrate from the graphene and halloysite clay. To date, nanoporous zeolites are the potential materials for gas separation based on a molecular sieving mechanism. A similar separation mechanism for hydrogen and helium from mixture gases may not work efficaciously due to the closeness of their kinetic diameter (H2: 2.89 Å and He: 2.6 Å). The presence of defects and torn nanopores between graphene layers along with the different surface charges of the inner and outer layer of halloysite nanotubes facilitates the ″coated″ membrane to show an appreciable H2/He separation factor of ∼4 using H2–He (1:1) mixture gas compared to 2.86 for the pure halloysite membrane. The available charge layer of graphene also has a significant contribution for this increased H2/He selectivity value. The permeate flux of H2 and He through both the graphene-coated clay membrane and pure clay membrane has also been noted. The permeate flux of pure H2 and He was 2 × 10–7 and 1.3 × 10–7 mol m–2 s–1 Pa–1 for the clay membrane, whereas for the ″coated″ clay membrane, the values changed to 0.1 × 10–7 and ∼0.05 × 10–7 mol m–2 s–1 Pa–1 at 100 kPa, respectively.

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