Single Dispersion of Fe(H2O)2‐Based Polyoxometalate on Polymeric Carbon Nitride for Biomimetic CH4 Photooxidation
Jing Ren,
Baifan Wang,
Hua‐Qing Yin
et al.
Abstract:Direct methane conversion to value‐added oxygenates under mild conditions with in‐depth mechanism investigation has attracted wide interest. Inspired by methane monooxygenase, the K9Na2Fe(H2O)2{[γ‐SiW9O34Fe(H2O)]}2·25H2O polyoxometalate (Fe‐POM) with well‐defined Fe(H2O)2 sites is synthesized to clarify the key role of Fe species and their microenvironment towards CH4 photooxidation. The Fe‐POM can efficiently drive the conversion of CH4 to HCOOH with a yield of 1570.0 μmol gPOM−1 and 95.8% selectivity at ambi… Show more
Acetaldehyde (AA) and ethylene oxide (EO) are important fine chemicals, also as the substrates with wide application for high-value chemical products. Direct electrocatalytic oxidation of ethylene to AA and EO...
Acetaldehyde (AA) and ethylene oxide (EO) are important fine chemicals, also as the substrates with wide application for high-value chemical products. Direct electrocatalytic oxidation of ethylene to AA and EO...
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