Single‐Crystal Transformation Engineering the Spin Change of Metal–Organic Frameworks via Cluster Deconstruction
Guang Yang,
Si‐Guo Wu,
Ze‐Yu Ruan
et al.
Abstract:Spin crossover (SCO) materials with new architectures will expand and enrich the research in the SCO field. Here, we report two metal–organic frameworks (MOFs) containing tetradentate organic ligands and hexatopic linkers [Ag8X8(CN)6]6− (X=Br and I), which represents the first SCO MOF with clusters as building blocks. The silver halide cluster can be further removed after reacting with lithium tetracyanoquinodimethan (LiTCNQ). Such post‐synthetic modification (PSM) is realized via single‐crystal to single‐crys… Show more
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