Abstract:The process of carbon capture, which is one of the most mature yet cost-intensive technology proposed to mitigate global warming has herein been explored as a potential strategy to generate dynamic ligands for metal separation and recovery. Spontaneous CO2 fixation by industrial amines such as diethylenetriamine affords dynamic arrays of interconverting species, from which tailored subsets can be selected yielding organometallic adducts of contrasted solubility. Quantitative compositional analyses of the phase… Show more
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