Simulation of Electrical Properties of Polymer Coatings on Metal Surface

Максимова, О. Г.; Baruzdina, O. S.; Maksimov, A. V.

doi:10.1080/00150193.2015.998114

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Calculation Of the Parameter Adhesion ã1

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2016

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“…The monomer can reach the surface of metal (that corresponds to the bottom of the potential well with the depth E c Þ, overcoming some energy barrier E b . 22,24 Then, the electron exchange between the monomers and the metal surface is possible. It leads to rather strong chemical bonds between them, i.e.…”

Section: Calculation Of the Parameter Adhesion ãmentioning

confidence: 99%

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Influence of interface on the formation process of polymer coatings on metal

2016

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The purpose of this work is in development of the model that allows to investigate the conformations of macromolecules near the interface \dielectric-metal" depending on the conditions of formation of the polymer coating. In the modified model of \sticky tape", one part of macromolecule is anchored to the metal surface while the other can be elongated due to effective mean (molecular) field of dipolar type formed by free ends of other chains. The dynamic Monte-Carlo method for Langmuir's model is used for calculation of adhesion force taking into account the interaction energy of monomers with the metal surface. It is shown that conformation of polymer chain is defined by temperature conditions of its formation. The obtained results are confirmed by the data of production tests on polymer coatings in JSC \Severstal".

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Section: Calculation Of the Parameter Adhesion ãmentioning

confidence: 99%

“…The self-consistency equation for the order parameter in the frame of the mean-field model 22 has the form:…”

Section: Modelmentioning

confidence: 99%