Additive manufacturing has been combined with commercially available RF materials to synthesize composite materials whose relative permittivity can be controlled. A design equation for predicting the effective permittivity of these composite materials has also been presented. The relative permittivity of the composite materials was measured by fabricating patch antennas using these materials as the substrate. It has been demonstrated that by using Taconic, PLA and air, three materials with different dielectric constants, a large and nearly continuous range of relative permittivity values, from 1.47 to 6.00, can be realised.Introduction: Materials whose relative permittivity can be controlled by the designer have the potential to be employed as antenna substrates and can enhance antenna performance [1]. Such materials are also an integral part of graded index (GRIN) devices. Graded index materials have their relative permittivity locally varied in order to achieve the desired electromagnetic response. These materials have been successfully implemented in the design of a five layer flat lens using field transformation with its performance superior to that of lens designed with ray optics [2]. These materials are also essential for transformation optics which is based on the principle of transforming the original coordinate system of an electromagnetic device in such a way that its electromagnetic behaviour remains unaltered when its shape changes. This is achieved by changing the refractive index (relative permittivity and permeability) in the coordinate space by using metamaterials and other artificially designed materials [3]. Low loss magnetic materials with relative permeability other than unity are extremely difficult to manufacture therefore the refractive index is generally controlled by varying the relative permittivity. This technique has been successfully applied to design a flat hyperbolic lens. The materials were designed from micro and nanoparticles of titanates using vaccuum casting [4]. Recently additive manufacturing using stereolithography was proposed to synthesize the artificial materials with controlled relative permittivity; however the range of the relative permittivities, for the synthesized material, was found to be limited (ranging from 2.12 to 3.08) [5]. In this letter the fused deposition modelling (FDM) technique has been used. FDM is very flexible and user friendly. It uses the stereolithography file (.stl) for manufacturing the desired structure, layer by layer. The material, in molten state, is extruded from the hot nozzle which then solidifies quickly after extrusion. This letter shows that by using FDM, additively manufactured structures can be combined with commercial laminates in order to achieve a wide range of permittivities. The resulting composite materials are three phase structures because three materials with different electromagnetic properties have been used for their synthesis. This allows for a larger range of relative permittivities which can be designed and synthesiz...