Can. J. Chem. 65, 1012(1987.To know the spatial distribution of ion pairs resulting from 63Ni P radiation in the gas phase is important for a variety of theoretical and practical reasons, in particular those concerning the electron capture detector. Literature estimates of this distribution vary by about one order of magnitude, yet this parameter is necessary for the modelling of this detector. The 63~i-induced, initial ion pair distribution was therefore measured in a variety of gases with two techniques: a conventional one based on the electrical saturation current at variable interelectrode distances, and an unconventional one based on luminescence from a plastic scintillator. The data are analyzed in terms of two ranges, d50 and d 9 5 , that describe the distances from a planar radioactive foil within which 50% and 95% of the total gas-phase ionization occur. The data from the electrical measurement show unexpected evidence of strong P backscattering and secondary electron emission from the counter-electrode. Under these (non-exponential) conditions, d50 values in the common detector gases nitrogen and argonlmethane vary from 0.5 to 1.0 mm, depending on the nature of the counter-electrode. Calculations based on the quasi-exponential range found at longer distances in electrical measurements yield values of about 2.5 mm (which are low because of geometric measurement bias). In contrast, the data from the luminescence measurement are almost completely exponential and d50 values for argon ( + 5 % methane) and nitrogen are 2.8 and 3.8 mm, respectively. The d95 values vary from 12 to 16 mm for the luminescence, to 6 and 9 mm for the (less reliable) electrical measurement; all at ambient conditions. The luminescence data are considered closer to the "true" (unimpeded) charge distribution, while the ionization data may be closer to the initial charge topography inside an electron capture detector of confining geometry. All range data, however, are short enough to advise modelling thc dctector as a system with strongly heterogeneous charge distribution. No evidence was found for some of the very large range estimates found in the literature. Conndtre la distribution spaciale des paires d'ions provenant de la radiation P du 6 3~i est important pour diverses raisons thtoriques et pratiques, en particulier celles concernant le dktecteur a capture d'klectrons. Les valeurs de la litterature, pour cette distribution, varient par environ un ordre de grandeur; pourtant ce parametre est nicessaire a la rtalisation d'un modkle de ce dktecteur. La distribution initiale des paires d'ions, induite par le 6 3~i fut donc mesurke dans divers gaz au moyen de deux techniques : I'une conventionnelle, basee sur le courant de saturation Clectrique a des distances interClectrodes variables; et l'autre peu conventionnelle, basee sur la luminescence d'un scintillateur en plastique. Les donnies sont analysies en fonction de deux distances, d50 et d 9 5 , qui decrivent les intervalles jusqu'ii une feuille radioactive planaire, a l'intkrieur...