Simple synthesis of acetogenin transoid insect pheromones starting from acetylcyclopropane

Cheskis, B. A.; Иванова, Н. М.; Moiseenkov, A. M.; Нефедов, О. М.

doi:10.1007/bf00961235

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2016

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“… a Estimated, ref . b At p /Pa = 267. c Ref . d Ref . e At p /Pa = 400. f Experimental, ref . g At p /Pa = 1.33 Pa. h Ref . i At p /Pa = 4. j Ref . k At p /Pa = 93.3. l Ref . m Vapor pressure at T /K = 293.2. n Ref . o Not available. p Ref . q Predicted value; SciFinder Scholar. r At p /Pa = 1333. s Ref . …”

Section: Resultsmentioning

confidence: 99%

Vaporization Enthalpies and Vapor Pressures of Some Insect Pheromones by Correlation Gas Chromatography

et al. 2016

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The vaporization enthalpies and vapor pressures of the following insect pheromones at T/K = 298.15 have been evaluated by correlation gas chromatography: Z-8-dodecenyl acetate, Z-4-tridecenyl acetate, E-11-tetradecenyl acetate, E,E-9,11-tetradecadienyl acetate, Sethyl (2E,4E)-3,7,11-trimethyl-2,4-dodecadienoate, R,S-2-propynyl (2E,4E)-3,7,11-trimethyl-2,4-dodecadienoate, and Z-13-octadecenyl acetate. Also evaluated are vapor pressures as a function of temperature from T/K = 298.15 to 500 which have been fit to a third-order polynomial. Normal boiling temperatures are predicted by extrapolation. The results are compared to available literature values.

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