Simple Preparation of Anatase TiO₂Nanoparticles via Pulsed Laser Ablation in Liquid

Abstract

The physical and chemical properties of TiO 2 have been of great interest due to the potential application in photocatalytic, photovoltaic, lithium-ion battery and dye-sensitized solar cell systems.1-3 Especially, its characteristic properties in optical and electronic properties, nontoxicity, chemical inertness, and high melting temperatures have drawn extensive research on the ability of semiconductor photocatalyst to promote the photodegradation of various pollutants. 4,5Anatase, brookite, and rutile are the major crystalline structures of TiO 2 , of which rutile phase is most stable; whereas anatase and brookite phases are metastable and easily transformed to rutile phase when heated above about 600-8006,7 As demonstrated in other experimental studies, the anatase form of TiO 2 has shown much higher photoactivity than that of rutile. 3,5,8,9 In the meantime, a number of methods have been explored and developed for the synthesis of TiO 2 nanoparticles, such as hydrolysis of Ti(IV) ions, 10 hydrolysis of titanium alkoxides 11 or titanium tetrachloride 12 in gas phase, sol-gel, 13hydrothermal hydrolysis, 14 and precipitation, 15 of which many studies were devoted to the synthesis of rutile phase, while fewer investigations on the anatase phase. This naively supports that synthesis of pure anatase phase is more challenging than that of rutile. Furthermore, the major products from the above techniques are typically amorphous and require post-calcination for better crystallinity and morphology of the product, which inevitably results in the formation of larger sizes of TiO 2 nanoparticles. Therefore, it is demanding to explore a method that overcomes the problems mentioned above.In order to fabricate small-sized TiO 2 nanoparticles with good crystallinity at room temperature, we have applied a pulsed laser to ablate a Ti plate immersed in deionized water and methanol. Pulsed laser ablation in liquid (PLAL) 16 was introduced by Patil and co-workers in 1987 and has been demonstrated to be an effective, simple, and versatile method for synthesizing nanomaterials starting from an appropriate choice of solids and liquids.17-20 Because of relatively simple and clean preparation of nanoparticles using PLAL, coupled with its versatility, many different metal nanostructures providing desired functions have been fabricated. One of the main advantages of PLAL compared to other methods is that it can generate nanomaterials without the need of any catalysts or organic additives. Hence, in recent years, PLAL has become a successful nanomaterial fabrication tool for the formation of the novel nanostructures.19,21-25 However, compared to large investigations on fabrication of TiO 2 by laser ablation in vacuum, 7,26-31 there were few studies on the preparation of TiO 2 nanoparticles by PLAL.32-34 Furthermore in the previous PLAL studies, the synthesis of rutile and mixture of anatase and rutile phase was mostly employed. 34,35In the present note, we report a one-step synthesis of pure anatase TiO 2 nanoparticles by PLA of Ti pla...

Effect of aging on the properties of TiO2 nanoparticle

“…Another reason for red shifting of the exitonic peak of NPs is their phase transition. k \ 200 nm is the wavelength that corresponds to the exitonic absorption peak of metastable TiO 2 nanoparticles, while after a week these peaks were shifted to around 300 nm which is the wavelength corresponding to exitonic absorption of rutile TiO 2 nanoparticles [16]. According to the results, the phase of TiO 2 nanoparticles was changed from metastable phase to rutile stable phase in a week.…”

Hybrid TiO2-ZnO Nanomaterials Prepared Using Laser Ablation in Liquid

“…The absorption in the UV region (below 300 nm) observed for the hybrid samples of TiO 2 /ZnO-2 and ZnO/TiO 2 -2 (both prepared at higher pulse energy) can also be assigned to metallic Zn inclusions, in accordance with XRD patterns where weak peaks for Zn were detected (Figure 1d). Both samples based on pure TiO 2 NPs (TiO 2 -1 and TiO 2 -2) show pronounced absorption peaks centered at 290-300 nm (see red spectra in Figure 11a,b) [23,25,50]. At the same time, the hybrid nanomaterials reveal wide absorption bands indicating a combination of both ZnO and TiO 2 NPs (see blue and green spectra in Figure 11a,b).…”

“…Nanomaterials of TiO 2 with different phase composition were reported by different groups, depending on the applied laser, energy fluence, and liquid media. For example, ablation of Ti metal by IR-nanosecond-pulsed laser in water and methanol was reported to produce anatase [23,24]. When the second harmonic (532 nm) of Nd:YAG nanosecond laser was applied in water, it gave a mixture of anatase and rutile [25], while the presence of surfactants was found to favor the growth of the rutile phase [16,26].…”

Ultra-bright emission from Sr doped TiO 2 nanoparticles through r-GO conjugation

“…Figure 5 shows the UV–Vis diffuse reflectance spectra of the prepared samples. As seen from figure 5, the absorbance of all the samples decreased in the range of 330–400 nm, and the absorption peak around 266 nm has been attributed due to the exciton absorption band [33–37]. With the doping of strontium and reduced graphene oxide, there was not much alteration in the absorption peak.…”