Simple electrodeposition of a novel lanthanide-based porous tri-metallic metal–organic framework grown onto Ni-foam support as a novel binder-free electrode for supercapacitors

Aghazadeh, Mustafa; Rad, Hamzeh Forati

doi:10.1007/s11581-022-04479-6

Cited by 12 publications

(3 citation statements)

References 35 publications

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“…2(b). Aghazadeh et al [120] synthesized TM-MOF via cathodic electrodeposition methodology using lanthanum, gadolinium and thulium as metallic precursors. A specific capacity of 412 C g -1 was reported at 1 A g -1 low current density achieving a rate capability of 52.9%.…”

Section: Tri-metallic Mofs For Supercapacitorsmentioning

confidence: 99%

Revolutionizing Energy Storage: Exploring Processing Approaches and Electrochemical Performance of Metal-Organic Frameworks (MOFs) and Their Hybrids

Khalid,

Karim,

Marwat

2024

J. Electrochem. Sci. Technol

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<p>The text highlights the growing need for eco-friendly energy storage and the potential of metal-organic frameworks (MOFs) to address this demand. Despite their promise, challenges in MOF-based energy storage include stability, reproducible synthesis, cost-effectiveness, and scalability. Recent progress in supercapacitor materials, particularly over the last decade, has aimed to overcome these challenges. The review focuses on the morphological characteristics and synthesis methods of MOFs used in supercapacitors to achieve improved electrochemical performance. Various types of MOFs, including monometallic, binary, and tri-metallic compositions, as well as derivatives like hybrid nanostructures, sulfides, phosphides, and carbon composites, are explored for their energy storage potential. The review emphasizes the quest for superior electrochemical performance and stability with MOF-based materials. By analyzing recent research, the review underscores the potential of MOF-based supercapacitors to meet the increasing demands for high power and energy density solutions in the field of energy storage.</p>

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Section: Tri-metallic Mofs For Supercapacitorsmentioning

confidence: 99%

Revolutionizing Energy Storage: Exploring Processing Approaches and Electrochemical Performance of Metal-Organic Frameworks (MOFs) and Their Hybrids

Khalid,

Karim,

Marwat

2024

J. Electrochem. Sci. Technol

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“…Besides, the electrical conductivity of multicomponent MOFs might be improved because the additional metal components would generate localized defects and thus result in electronic delocalization in MOFs. [57] Therefore, bimetallic MOFs, [32,[57][58][59][60] multimetallic MOFs, [61] and polyoxometalate-based MOFs, [62,63] have all attracted extensive attention. In recent years, the amorphous MOFs engineering has also been demonstrated to be a powerful way to enhance the electrochemical performance due to the higher conductivity, more accessible defective sites, and more open and disordered channels than the pristine MOF.…”

Section: Mofs Selectionmentioning

confidence: 99%

Recent Progress of Advanced Conductive Metal–Organic Frameworks: Precise Synthesis, Electrochemical Energy Storage Applications, and Future Challenges

Zhu

Gao

2022

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inherent disadvantage of unstable output, which means electrochemical energy storage and conversion devices are essential for storing and utilizing these energies at any time. [6] Supercapacitors (SCs), lithium-ion batteries (LIBs), lithium-sulfur (Li-S) batteries, and electrochemical water splitting can efficiently convert electricity into chemical energy for storage and thus have received extensive attention. [7] The performance of the energy storage devices mainly depends on the electrode materials and the performance of energy conversion devices mainly depends on catalysts. Therefore, the development of high-performance electrode materials and electrocatalysts is crucial.Metal-organic frameworks (MOFs), also known as porous coordination polymers, are a new type of porous crystalline material. [8] Obtained by bridging metal ions or clusters and organic ligands via well-defined coordination bonds, MOFs possess unique structures with ultrahigh specific surface area, tunable composition, adjustable pore structure, and abundant exposed active sites, exhibiting significant potential for applications in gas storage and separation, catalysis, sensing, and energy storage. [9,10] The regular open pore structures of MOFs enable them to effectively contact electrolytes and alleviate volume expansion during charging and discharging when serving as electrodes. Besides, the abundant exposed active sites and the ultrahigh specific surface area of MOFs can meet the performance requirements of electrocatalysts for water splitting and electrode materials for SCs and LIBs, the plentiful polar sites and the complex pore structure of MOFs can effectively adsorb polysulfides as sulfur host. [11,12] Therefore, in recent years, great efforts have been devoted to the use MOFs as electrode materials for supercapacitors, anode materials for LIBs, sulfur hosts for Li-S batteries, and electrocatalysts for water splitting.The pristine MOFs possess numerous electrochemically active sites, which are almost fully accessible due to the regular pore structures. However, MOFs are usually composed of metal ions and redox-inactive organic ligands, lack free charge carriers, and charge transport paths, and thus are mostly electrically insulating, meaning that only the part in contact with current collectors or conductive additives can gain electrons to participate in the reaction, resulting in low utilization of Metal-organic frameworks (MOFs) with diverse composition, tunable structure, and unique physicochemical properties have emerged as promising materials in various fields. The tunable pore structure, abundant active sites, and ultrahigh specific surface area can facilitate mass transport and provide outstanding capacity, making MOFs an ideal active material for electrochemical energy storage and conversion. However, the poor electrical conductivity of pristine MOFs severely limits their applications in electrochemistry. Developing conductive MOFs has proved to be an effective solution to this problem. This review focuses on the design and syn...

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“…Recently, metal-organic framework materials (MOFs) are crystalline porous materials with a cyclical meshwork structure shaped by self-assembly of transition metal ions and organic ligands, mainly consisting of two important components: connectors and linkers. [24][25][26] With a nanoscale skeleton structured pore structure, high specic surface area and low solid density, they have shown excellent performance in adsorption, separation, catalysis and other aspects, and have become an investigation focus and frontier in the area of new materials. [27][28][29][30] The synthetic method of porous transition metal phosphide electrodes with MOFs as the precursor or template has also attracted extensive attention.…”

Section: Introductionmentioning

confidence: 99%

MOF-derived carbon coated Cu₃P with Ni doping as advanced supercapacitor electrode materials

Jin

Jia

et al. 2022

Sustainable Energy Fuels

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Simple electrodeposition of a novel lanthanide-based porous tri-metallic metal–organic framework grown onto Ni-foam support as a novel binder-free electrode for supercapacitors

Cited by 12 publications

References 35 publications

Revolutionizing Energy Storage: Exploring Processing Approaches and Electrochemical Performance of Metal-Organic Frameworks (MOFs) and Their Hybrids

Revolutionizing Energy Storage: Exploring Processing Approaches and Electrochemical Performance of Metal-Organic Frameworks (MOFs) and Their Hybrids

Recent Progress of Advanced Conductive Metal–Organic Frameworks: Precise Synthesis, Electrochemical Energy Storage Applications, and Future Challenges

MOF-derived carbon coated Cu₃P with Ni doping as advanced supercapacitor electrode materials

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Simple electrodeposition of a novel lanthanide-based porous tri-metallic metal–organic framework grown onto Ni-foam support as a novel binder-free electrode for supercapacitors

Cited by 12 publications

References 35 publications

Revolutionizing Energy Storage: Exploring Processing Approaches and Electrochemical Performance of Metal-Organic Frameworks (MOFs) and Their Hybrids

Revolutionizing Energy Storage: Exploring Processing Approaches and Electrochemical Performance of Metal-Organic Frameworks (MOFs) and Their Hybrids

Recent Progress of Advanced Conductive Metal–Organic Frameworks: Precise Synthesis, Electrochemical Energy Storage Applications, and Future Challenges

MOF-derived carbon coated Cu3P with Ni doping as advanced supercapacitor electrode materials

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MOF-derived carbon coated Cu₃P with Ni doping as advanced supercapacitor electrode materials