2019
DOI: 10.1016/j.aca.2018.10.005
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Simple and sensitive fluorescence sensor for methotrexate detection based on the inner filter effect of N, S co-doped carbon quantum dots

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Cited by 108 publications
(43 citation statements)
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“…Most of the rapid detection of pesticides is achieved by monitoring their enzyme inhibition activity, however, a variety of pesticides can inhibit a particular enzyme leading to poor selectivity. However, with the recent development in 0-D nanomaterials, the interactions of pesticides with fluorescent CQDs have been reported to influence the fluorescence intensity depending upon the nature of interaction [51][52][53][54][55], which can be utilized as a transduction mechanism. Interaction of pesticides with CQDs leading to the perturbation of the recombination electronehole pair, different types of charge transfer, energy transfer, and IFE can lead to fluorescence change of CQDs.…”
Section: Detection Of Pesticidesmentioning
confidence: 99%
“…Most of the rapid detection of pesticides is achieved by monitoring their enzyme inhibition activity, however, a variety of pesticides can inhibit a particular enzyme leading to poor selectivity. However, with the recent development in 0-D nanomaterials, the interactions of pesticides with fluorescent CQDs have been reported to influence the fluorescence intensity depending upon the nature of interaction [51][52][53][54][55], which can be utilized as a transduction mechanism. Interaction of pesticides with CQDs leading to the perturbation of the recombination electronehole pair, different types of charge transfer, energy transfer, and IFE can lead to fluorescence change of CQDs.…”
Section: Detection Of Pesticidesmentioning
confidence: 99%
“…This could provide some evidences for the occurrence of internal lter effects (IFE). 35,36 In addition, to further verify the possibility of the IFE mechanism, the uorescence lifetimes of AA-Cu NCs was analyzed in the absence and presence of quercetin, respectively. As Fig.…”
Section: Determination Mechanismmentioning
confidence: 99%
“…The effective IFE demands a complementary/overlap of the absorption spectrum of the absorbers and excitation and/or emission spectra of uorophores. 8,[45][46][47] A good overlap between the emission spectrum of the as-prepared N-CDs and absorption band of Co 2+ was observed, which conrmed the IFE mechanism of Co 2+ sensing. Furthermore, the average uorescence lifetimes of N-CDs and N-CDs/Co 2+ were 3.53 ns and 3.60 ns, respectively, as shown in Fig.…”
Section: Fluorescent Detection Of Co 2+mentioning
confidence: 61%