Naturally occurring halloysite nanotubes (HNTs) have
attracted
significant scientific interest due to their multifunctional behavior
and biocompatibility. However, the application of HNTs in photonics
is still unexplored. Here, natural HNTs with different lengths and
diameters have been employed as passive scatterers for the generation
of random laser (RL) emission from rhodamine B (RhB) in a colloidal
phase. Upon pumping at 532 nm, mixed HNT-RhB disordered colloidal
systems are shown to yield orange RL emission with a linewidth as
small as ∼4 nm. Moreover, a statistical analysis of shot-to-shot
correlations among RL modes reveals an obvious photonic paramagnetic
to spin-glass transition with increasing pump energy, which is a unique
statistical fingerprint of RL. Interestingly, besides acting as scatterers,
the HNTs are also found to improve the photostability of RhB molecules.
Indeed, HNTs help to better dissipate the excess energy deposited
in the gain medium, thus protecting the dye from photodegradation
and facilitating the achievement of RL. The results contribute to
the theoretical understanding and technical development of low-cost
RL devices based on widely available sources in view of multiple prospective
applications in photonics.