2006
DOI: 10.1063/1.2357548
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Silver nanocrystal superlattice coating for molecular sensing by surface-enhanced Raman spectroscopy

Abstract: A nanotechnique to assemble silver nanocrystals and control the gaps precisely in the sub-10 nm regime is demonstrated on an active coating exhibiting surface-enhanced Raman scattering ͑SERS͒. The silver nanocrystal superlattice coating boasts a high SERS enhancement factor, large dynamic range, and universal SERS activity. The observed SERS efficiency can be explained in terms of interparticle-coupling-induced Raman enhancement.

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Cited by 38 publications
(28 citation statements)
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“…[26] Although small NPs/nanocrystals of Au and Ag are usually considered having low intrinsic Raman cross-section, the assemblies or superlattices formed by these nanocrystals have shown good SERS activity. [27] Direct measurement of the Raman spectrum of the GPS gives a typical SERS spectrum of DNA ( Figure S11, Supporting Information).…”
Section: Electrochemical and Sers Response Of The I-motif-gps Upon Vamentioning
confidence: 99%
“…[26] Although small NPs/nanocrystals of Au and Ag are usually considered having low intrinsic Raman cross-section, the assemblies or superlattices formed by these nanocrystals have shown good SERS activity. [27] Direct measurement of the Raman spectrum of the GPS gives a typical SERS spectrum of DNA ( Figure S11, Supporting Information).…”
Section: Electrochemical and Sers Response Of The I-motif-gps Upon Vamentioning
confidence: 99%
“…However, an outstanding challenge of SERS‐based detection is the lack of robust and facile fabrication routines for SERS substrates with considerable enhancements. Traditionally, electrochemically roughened metal surfaces,18 colloids,19 island films,20, 21 nanowires,22 periodic arrays,23, 24 and self‐assembled nanoparticles25, 26 are employed as SERS substrates (for a recent review, see Reference 27). However, the long‐term stability of aggregated nanoparticles is the main obstacle for assembled structures, and the fabrication of complex surface structures (e.g.…”
mentioning
confidence: 99%
“…The corresponding SERS enhancement factor is ca. 1.8 Â 10 8 , which is far higher than those of 1 Â 10 5 and 1 Â 10 6 reported in the SERS studies [44,45] based on Ag nanocrystals on Si [44] and Au-coated ZnO nanorods [45], respectively. The Electron transfer from the electron-hole pairs of TiO 2 NPs to the TiO 2 -adsorbed positively charged Au ions was responsible for the preparation of highly SERS-active Au/TiO 2 films on the substrate using photoreduction under UV light of 310 nm.…”
Section: Discussionmentioning
confidence: 51%