2014
DOI: 10.1007/s10008-014-2503-2
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Silver migration at the Ag|Sm0.2Ce0.8O1.9 interface

Abstract: The behavior of a silver electrode contacting Ce 0.8 Sm 0.2 O 1.9 (samaria-doped ceria or SDC) electrolyte under external cathodic polarization in the temperature range 350-700°C was examined by means of long-term polarization experiments, scanning electron microscopy, and electrochemical impedance spectroscopy. A silver deposit is formed around the silver cathode via a surface migration mechanism without the occurrence of the gas-phase transport phenomenon during polarization. This results in an increase in b… Show more

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Cited by 2 publications
(1 citation statement)
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“…Various sources of biomass have been investigated as fuels for DCFCs, including pyrolyzed pine, [6][7] acacia and beech wood, 18 oak sawdust, 19 olive wood, 20 and pyrolyzed medium density fiberboard. 21 The electrochemical performances (I-V-P curves) of synthetic carbon (C black), and bituminous coal (B-II) 22 were contrasted with a biomass fuel, locally sourced charcoal, at 755 • C under 80:20 vol% N 2 :CO 2 in this work.…”
Section: Resultsmentioning
confidence: 99%
“…Various sources of biomass have been investigated as fuels for DCFCs, including pyrolyzed pine, [6][7] acacia and beech wood, 18 oak sawdust, 19 olive wood, 20 and pyrolyzed medium density fiberboard. 21 The electrochemical performances (I-V-P curves) of synthetic carbon (C black), and bituminous coal (B-II) 22 were contrasted with a biomass fuel, locally sourced charcoal, at 755 • C under 80:20 vol% N 2 :CO 2 in this work.…”
Section: Resultsmentioning
confidence: 99%