Silver(I) Complexes of 12‐Phenylalkynyl‐ and 12‐Triisopropylalkynylcarba‐closo‐dodecaborate Anions

Nonclassical Applications of closo-Carborane Anions: From Main Group Chemistry and Catalysis to Energy Storage

“…119 Most recently, Finze and co-workers have reported that capping the end of the alkyne functionality with a Ph or iPr 3 Si group allowed for the formation simpler monomeric and dimeric Ag complexes. 120…”

“…These compounds, exemplified by 67 , showed exceptional phosphorescent properties for Ag­(I) clusters . Most recently, Finze and co-workers have reported that capping the end of the alkyne functionality with a Ph or i Pr 3 Si group allowed for the formation simpler monomeric and dimeric Ag complexes …”

Sonogashira coupling of the ethynyl monocarborane [CB11H11-12-CCH]−

“…They can be used to form side-on mononuclear metal complexes with Cu(I) and Ag(I) (Fig. 2b), 33,34 but they also enable formation of structurally versatile, highly luminescent multinuclear assemblies with sideon as well as end-on metal interactions with Cu(I), Ag(I), and Au(I). [35][36][37][38][39][40] Additionally, electronic effects and electrochemical trends in alkynyl monocarboranes were studied.…”

Silver(I) Clusters Stabilized by the Carba‐closo‐dodecaboranylethynyl Ligand with O‐Donor Coligands and Template Ions

“…[7] More often, the {closo-1-CB 11 } cluster is bonded to a functional group that binds to the metal. Phosphanes, [9] nitriles, [10] N-heterocyclic carbenes, [11] and alkynes [12][13][14][15][16][17][18] with carba-closo-dodecaboranyl groups are recent examples for such derivatives.…”