2014
DOI: 10.1016/j.jpowsour.2014.05.096
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Silicon-based materials as high capacity anodes for next generation lithium ion batteries

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Cited by 507 publications
(349 citation statements)
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“…Unfortunately, at full lithiation a Si particle expands by 270% and this presents significant structural stability challenges at the level of the entire electrode. During lithiation, Si particles expand and encroach on each other and during delithiation, Si particles contract, which can result in detachment from surrounding electrical connections [90]. Such a drastic electrode morphology change can further contribute to capacity fading.…”
Section: 2-a Promising Anode Material: Siliconmentioning
confidence: 99%
“…Unfortunately, at full lithiation a Si particle expands by 270% and this presents significant structural stability challenges at the level of the entire electrode. During lithiation, Si particles expand and encroach on each other and during delithiation, Si particles contract, which can result in detachment from surrounding electrical connections [90]. Such a drastic electrode morphology change can further contribute to capacity fading.…”
Section: 2-a Promising Anode Material: Siliconmentioning
confidence: 99%
“…Total weight of EV battery packs can be reduced by replacing their primary component, i.e., the battery cells with cells made of novel materials that possess greater gravimetric capacity (mAh/g) or demonstrate a higher operating voltage than traditional active materials [53,54]. However, increase in gravimetric density of electrode materials cannot be scaled linearly to be reflected as nominal capacity of commercial battery cells due to the non-negligible weight of inactive cell components.…”
Section: Light Weightmentioning
confidence: 99%
“…The subsequent discharging step (I max = 140 ”A, upper voltage limitation of 1 V) complements the formation procedure. The procedure applied ensured a homogeneous formation of the solid electrolyte interface (SEI) [16]. Furthermore, it represents a standardized sequence allowing for a reasonable comparison with the reference sample using silicon without any barrier material.…”
Section: Electrochemical LI Ion Stressingmentioning
confidence: 99%