Silicon-based anodes for lithium-ion batteries: Effectiveness of materials synthesis and electrode preparation

Abstract

Lithium-ion batteries are widely used throughout the world for portable electronic devices and mobile phones and show great potential for more demanding applications like electric vehicles. Unfortunately, lithium-ion batteries still lack the required level of energy storage to completely meet the demands of such applications as electric vehicles. Among advanced materials being studied, silicon nanoparticles have demonstrated great potential as an anode material to replace the commonly used graphite. Silicon has been shown to have a high theoretical gravimetric capacity, approximately 4200 mAh/g, compared to only 372 mAh/g for graphite. Though silicon nanoparticles have remarkably high capacity, they suffer from rapid degradation with each cycle due to electrode volume expansion of approximately 400% during lithiation, placing a large strain on the material. With each cycle that strain creates cracks in the electrode particles and causes them to break down into smaller particles, which create void spaces between the particles and lead to poor contact as reflected in poor conductivity. In this review, we discuss exciting new research on silicon-based anodes conducted during the past couple of years. Besides stressing the importance of well-designed nanostructures of Si, we focus on optimization of the Si electrode and resulting performance enhancement by properly selecting binders and synergistically integrating them with various carbon materials during electrode design and fabrication. Importantly, although each improvement strategy has its own advantage, appropriate combination of them will yield much higher anode performance. We summarize the core issues in developing the silicon anode and effective strategies in yielding more promising results. 3 Content: 1. Introduction crystallinity of Si after cycling. (g) Initial cycling behaviors of Si particles in different conductive matrixes against lithium metal counter electrodes at C/10 rate. Reprinted with permission from Ref. [50]. Copyright 2011, Wiley-VCH.. directly on the current collector, which do not pulverize or break into smaller particles after cycling. Rather, facile strain relaxation in the nanowires allows them to increase in diameter without breaking. (c) Voltage profiles for the Si nanowires cycled at different currents. (d) Capacity versus cycle number for the Si nanowires at the C/20 rate. (e and f) SEM image of pristine Si nanowires before (e) and after (f) electrochemical cycling. Reprinted with permission from Ref. [31, 66].

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