2022
DOI: 10.1063/5.0099789
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Significant π bonding in coinage metal complexes OCTMCCO− from infrared photodissociation spectroscopy and theoretical calculations

Abstract: A series of coinage metal complexes in the form of TMC(CO)n- (TM=Cu, Ag, Au; n = 0-3) were generated using a laser ablation-supersonic expansion ion source in the gas phase. Mass-selected infrared photodissociation spectroscopy in conjunction with quantum chemical calculations indicated that the TMC(CO)3- complexes contain a linear OCTMCCO- core anion. Bonding analyses suggest that the linear OCTMCCO- anions are better described as the bonding interactions between a singlet ground state TM+ metal cation and th… Show more

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