Short Total Synthesis of (+)-Colletotryptins B-D and Mucronatin B Derivative
Wilailak Saetae,
Chayamon Chantana,
Saowanit Saithong
et al.
Abstract:The short and first total synthesis of (+)-colletotryptins B-D, ent-colletotryptin A, and diastereomer of mucronatin B, which are a group of natural 3-(indol-2-yl)-3-(indol-3-yl)-1,2-propanediol (IIPDO) analogues containing two stereogenic centers at the C8′ and C9′ positions, isolated from endophytic fungus Colletotrichum sp. SC1355 and Tetrapterys mucronata, respectively, has been successfully accomplished in two and three steps with overall yields ranging from 28 to 54%. Key features of this synthesis inclu… Show more
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