Motivated by an increasing number of remarkable experimental observations on the role of pressure and shear stress in solid reactions, explosions, and detonations, we present a simple one-dimensional model that embodies nonlinear elasticity and dispersion as well as chemical or phase transformation. This generalization of the Toda lattice provides an effective model for the description of the organization during an abrupt transformation in a solid. One of the challenges is to capture both the equilibrium degrees of freedom as well as to quantify the possible role of out-of-equilibrium perturbations. In the Toda lattice, we verify that the particle velocities converge in distribution towards the Maxwell-Boltzmann distribution, thus allowing us to define a bonafide temperature. In addition, the balance between nonlinearity and wave dispersion may create solitary waves that act as energy traps. In the presence of reactive chemistry, we show that the trapping of the released chemical energy in solitary waves that are excited by an initial perturbation provides a positive feedback that enhances the reaction rate and leads to supersonic explosion front propagation. These modes of rupture observed in our model may provide a first-order description of ultrafast reactions of heterogeneous mixtures under mechanical loading. DOI: 10.1103/PhysRevE.65.026609 PACS number͑s͒: 43.25.ϩy, 81.40.Np, 62.50.ϩp
I. EXPERIMENTAL MOTIVATIONSDiffusion transfers of mass or heat usually control front propagation associated with solid phase chemical reactions or phase transformations. As a consequence, the velocity of fronts is small and even negligible compared to the sound velocities of the reactants and of the products. Typical solidsolid reactions such as TaϩC→TaC or solid-liquid reactions such as 2AlϩFe 2 O 3 →Al 2 O 3 ϩ2Fe, characterized by extremely high activation energies, can react in the combustion mode and these rates are determined by the preheating of reactants by thermal conduction. The combustion front velocity is proportional to ͱ/, where the thermal diffusivityand the characteristic reaction time ϭ1/k 0 e ϪE/RT ad ϷO(10 Ϫ2 ). Therefore, the reaction front velocity is of the order of ϰͱ/ϷO(10 Ϫ2 ) m/s. Thus, diffusive transfer cannot explain events propagating at front velocities much faster than cm/s, such as detonations or deflagrations, explosive recrystallization, photoinduced reactions, and the highpressure heterogeneous reactions studied by Bridgman in his pioneering work and later by Enikolopyan.The ultrafast reaction of heterogeneous mixtures under mechanical loading is particularly intriguing. In 1935, Bridgman reported results of combined hydrostatic pressure and shear for a wide variety of materials ͓1͔. Whilst most substances underwent polymorphic transformation, some reacted rather violently. In contrast to PbO, that decomposed quiescently to a thin film of lead, PbO 2 detonated and residue of Pb was found afterwards. Reactive mixtures produced even more violent results: Stoichiometric mixtures of Cu and S det...