The level structure of odd-odd 134 Sb has been studied at CERN/ISOLDE following the β − decay of 134 Sn and the β-delayed neutron decay of 135 Sn. Elemental and isobaric separation were accomplished by use of a resonance ionization laser ion source and an on-line mass separator, respectively. Both γ -ray singles and γ -γ coincidence data were taken as a function of time. New levels at 279, 441, 555, 617, and 1385 keV have been identified and given proposed spin and parity assignments of 7 − , 5 − , 6 − , 4 − , and 5 − , respectively, following β-delayed neutron decay of 7/2 − 135 Sn. New 1 − levels have been identified at 1900, 2170, and 2430 keV following the β − decay of 0 + 134 Sn. The resulting level structures are compared to shell-model calculations using the CD Bonn interaction and scaled and unscaled Kuo-Herling interactions developed for the 208 Pb region. Remarkably enough, the unscaled Kuo-Herling interaction provides the best fit for the levels below 1 MeV.