[1] In order to investigate the processes responsible for the attenuation of seismic shear waves in the Earth's upper mantle, four olivine polycrystals ranging in mean grain size d from 3 to 23 mm have been fabricated, characterized, and mechanically tested in torsion at high temperatures and seismic frequencies. Both the shear modulus, which governs the shear wave speed V S , and the dissipation of shear strain energy Q À1 have been measured as functions of oscillation period T o , temperature T, and, for the first time, grain size. At sufficiently high T all four specimens display similar absorption band viscoelastic behavior, adequately represented for 1000 < T < 1200 or 1300°C and 1 < T o < 100 s, by the expression] a with A = 7.5 Â 10 2 s Àa mm a , a = 0.26 and E = 424 kJ mol À1 . This mildly grain-size-sensitive viscoelastic behavior of melt-free polycrystalline olivine is attributed to a combination of elastically and diffusionally accommodated grain boundary sliding, the latter becoming progressively more important with increasing T and/or T o . Extrapolation to the larger (mm-cm) grain sizes expected in the Earth's upper mantle yields levels of dissipation comparable with those observed seismologically, implying that the same grain-size-sensitive processes might be responsible for much of the observed seismic wave attenuation. The temperature sensitivity of V S is increased substantially by the viscoelastic relaxation allowing the lateral variability of wave speeds to be associated with relatively small temperature perturbations.