We present numerical results of electric conductivity σ el of a fluid obtained solving the Relativistic Transport Boltzmann equation in a box with periodic boundary conditions. We compute σ el using two methods: the definition itself, i.e. applying an external electric field, and the evaluation of the Green-Kubo relation based on the time evolution of the current-current correlator. We find a very good agreement between the two methods.We also compare numerical results with analytic formulas in Relaxation Time Approximation (RTA) where the relaxation time for σ el is determined by the transport cross section σtr, i.e. the differential cross section weighted with the collisional momentum transfer. We investigate the electric conductivity dependence on the microscopic details of the 2-body scatterings: isotropic and anisotropic cross-section, and massless and massive particles. We find that the RTA underestimates considerably σ el ; for example at screening masses mD ∼ T such underestimation can be as large as a factor of 2. Furthermore, we study a more realistic case for a quark-gluon system (QGP) considering both a quasi-particle model, tuned to lQCD thermodynamics, as well as the case of a pQCD gas with running coupling. Also for these cases more directly related to the description of the QGP system, we find that RTA significantly underestimate the σ el by about a 60 − 80%.