2013
DOI: 10.1155/2013/631350
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Shape‐Controlled Metal Nanoparticles and Their Assemblies with Optical Functionalities

Abstract: Metal nanoparticles (NPs) possess excellent optical, optoelectronic, and optochemical properties based on their surface plasmon resonance. However, for practical use, the morphology and assembly of metal NPs need to be controlled. Here, we review facile control methods including seed-mediated growth accompanied with a comproportionation reaction of seeds to control their morphology and assembly. Several synthetic conditions have been modified to precisely control the morphology of metal NPs. Functionalized mes… Show more

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Cited by 35 publications
(17 citation statements)
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“…Gold nanoparticles have led the world of nanotheranostics with their unique physical and chemical properties. Ranging in diameter from small clusters of 2–5 nm up to 100 nm, AuNPs can be synthesized in different shapes such as spheres, hollow, rods, diamonds, prisms, cages, either single solid bodies or in a core shell format [ 26 , 27 ]. Each combination of size and shape shows slightly different properties that may be explored for theranostic purposes, such as optical properties from intense bright colors, contrast agents and photothermal capability in the infrared (IR) and near infrared (NIR), biofunctionalization potential and toxicity [ 20 , 28 ].…”
Section: Focus On Goldmentioning
confidence: 99%
“…Gold nanoparticles have led the world of nanotheranostics with their unique physical and chemical properties. Ranging in diameter from small clusters of 2–5 nm up to 100 nm, AuNPs can be synthesized in different shapes such as spheres, hollow, rods, diamonds, prisms, cages, either single solid bodies or in a core shell format [ 26 , 27 ]. Each combination of size and shape shows slightly different properties that may be explored for theranostic purposes, such as optical properties from intense bright colors, contrast agents and photothermal capability in the infrared (IR) and near infrared (NIR), biofunctionalization potential and toxicity [ 20 , 28 ].…”
Section: Focus On Goldmentioning
confidence: 99%
“…Noble metal nanoparticles have attracted much attention in the last decades because they can be prepared through simple and versatile methods resulting in nm sized nanostructures whose dimension and shape finely tune their optical and electronic properties [1][2][3]. The nm sized particles show an intense optical response determined by the surface plasmon resonance (SPR), whose frequency and spectral broadening can be controlled by the shape, composition, and concentration of the colloidal nanomaterial [4,5].…”
Section: Introductionmentioning
confidence: 99%
“…Since the optical properties of these particles depend on their sizes and shapes, one of the desired goals is to control the shapes of metal and semiconductor nanoparticles. Shape control has been successfully demonstrated for gold nanoparticles using nonionic surfactants, silver underpotential deposition, and nanoreplica molding [8][9][10][11]. Nanoreplica molding has been demonstrated as a low-cost method for manufacturing a variety of devices comprised of nano structured surfaces.…”
Section: Introductionmentioning
confidence: 99%