“…In the central areas and surroundings, the highest heat flux values of the Larderello geothermal area have been measured, reaching up to ∼1,000 mW m − 2 (Della Vedova et al, 2001), with soil temperatures reaching up to ∼98°C in correspondence with geothermal emergencies (Cabassi et al, 2021;Taussi et al, 2022). These conditions mainly occur along an NNE-striking fault zone, at least 5 km long, that runs from Monterotondo Marittimo to Sasso Pisano Granieri et al, 2023;Hooker et al, 1985;Leila et al, 2021;Minissale et al, 1997;Panichi & Tongiorgi, 1975;Tassi et al, 2012;Venturi et al, 2019) and geothermal wells (Gherardi et al, 2005;Magro et al, 2003); (c) dot-map of the Rc/Ra values measured in natural emissions (data from Hooker et al, 1985;Minissale et al, 1997;Magro et al, 2003) and geothermal wells (Gherardi et al, 2005;Hooker et al, 1985;Magro et al, 2003); (d) distribution of degassing rates computed in this work for central and peripheral areas. The black dashed lines circumscribe the location of most of the geothermal wells drilled in the area (after www.geothopica.igg.cnr.it).…”