Understanding flow, transport, chemical
reactions, and hydromechanical
processes in fractured geologic materials is key for optimizing a
range of subsurface processes including carbon dioxide and hydrogen
storage, unconventional energy resource extraction, and geothermal
energy recovery. Flow and transport processes in naturally fractured
shale rocks have been challenging to characterize due to experimental
complexity and the multiscale nature of quantifying continuum scale
descriptions of mass exchange between micrometer-scale fractures and
nanometer-scale pores. In this study, we use positron emission tomography
(PET) to image the transport of a conservative tracer in a naturally
fractured Wolfcamp shale core before and after the core was exposed
to low pH brine conditions. Image-based experimental observations
are interpreted by fitting an analytical transport model to fracture-containing
voxels in the core. Results of this analysis indicate subtle increases
in matrix diffusivity and a slightly more uniform fracture velocity
distribution following exposure to low pH conditions. These observations
are compared with a multicomponent one-dimensional reactive transport
model that indicates the capacity for a 10% increase in porosity at
the fracture-matrix interface as a result of the low pH brine exposure.
This porosity change is the result of the dissolution of carbonate
minerals in the shale matrix to low pH conditions. This image-based
workflow represents a new approach for quantifying spatially resolved
fracture-matrix transport processes and provides a foundation for
future work to better understand the role of coupled transport, reaction,
and mechanical processes in naturally fractured rocks.