“…In other words, the composition and structure of phases in a sample after severe plastic deformation can differ from those before deformation. In particular, the decomposition of supersaturated solid solutions [2,[5][6][7], the satura tion of the matrix with the second component (forma tion of solid solutions) [6,7], the formation of one or two different amorphous phases from crystalline phases [8][9][10], the decomposition of an amorphous phase with the formation of nanocrystals [11,12], and allotropic phase transformations (e.g., α-ε Co, α-γ Fe, α-β-ω Ti, or α-β-ω Zr) [2,4,[13][14][15][16] can occur. However, all listed phenomena were observed in phases with a relatively simple crystal lattice such as an fcc lattice with the space group Fm3m, a bcc lattice with the space group Im3m, and an hcp lattice with the space group P63.…”
“…In other words, the composition and structure of phases in a sample after severe plastic deformation can differ from those before deformation. In particular, the decomposition of supersaturated solid solutions [2,[5][6][7], the satura tion of the matrix with the second component (forma tion of solid solutions) [6,7], the formation of one or two different amorphous phases from crystalline phases [8][9][10], the decomposition of an amorphous phase with the formation of nanocrystals [11,12], and allotropic phase transformations (e.g., α-ε Co, α-γ Fe, α-β-ω Ti, or α-β-ω Zr) [2,4,[13][14][15][16] can occur. However, all listed phenomena were observed in phases with a relatively simple crystal lattice such as an fcc lattice with the space group Fm3m, a bcc lattice with the space group Im3m, and an hcp lattice with the space group P63.…”
“…SPD also induces various phase transformations [12] such as formation [13][14][15] or decomposition [16][17][18][19][20] of supersaturated solid solution, dissolution of particles of a second solid phase [21][22][23][24][25][26], amorphization [27][28][29][30][31][32] and nanocrystallization [33][34][35]. Among this variety, very interesting are the phase transformations with formation of high-pressure phases.…”
Abstract:The pressure influence on the α → ω transformation in Ti-Co alloys has been studied during high pressure torsion (HPT). The α → ω allotropic transformation takes place at high pressures in titanium, zirconium and hafnium as well as in their alloys. The transition pressure, the ability of high pressure ω-phase to retain after pressure release, and the pressure interval where α and ω phases coexist depend on the conditions of high-pressure treatment. During HPT in Bridgeman anvils, the high pressure is combined with shear strain. The presence of shear strain as well as Co addition to Ti decreases the onset of the α → ω transition from 10.5 GPa (under quasi-hydrostatic conditions) to about 3.5 GPa. The portion of ω-phase after HPT at 7 GPa increases in the following sequence: pure Ti → Ti-2 wt % Co → Ti-4 wt % Co → Ti-4 wt % Fe.
“…Our and above-described literature data suggest that conditions for the formation of nanoclusters of the crystal phase arise during strain in the Bridgeman chamber already on application of the compression. Typically, MPS in the Bridgeman chamber is structurally manifested through the formation of highly localized shear bands in which high stress level, local temperature increase, and high free volume concentration are observed [12]. It seems likely that nanoclusters that are in the region subjected to the action of the shear bands grow transforming into nanocrystals due to the increase of the temperature inside of them and of the free volume in the strained regions as well as due to the increased dynamic mobility of atoms.…”
The structure evolution of the Zr 50 Ni 18 Ti 17 Cu 15 massive metal glass upon megaplastic strain (MPS) in the Bridgeman chamber is investigated in a wide interval of strain degrees at room temperature. It is demonstrated that upon MPS with n = 1/2 rotation of the Bridgeman anvil, nanocrystalline phases are precipitated in the alloy. With increasing strain, these phases are dissolved. It is suggested that nucleation centers of nanocrystalline phases (nanoclusters) are formed in the amorphous matrix upon MPS under compression without shear in the Bridgeman chamber. These phases grow in the shear bands transforming into the nanocrystalline phase upon MPS.
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