Single Crystals of Nd 1−x Ca 1+x MnO 4 have been prepared by the traveling floating-zone method, and possible evidence of a charge -orbital density wave in this material presented earlier [PRB68,092405 (2003)] using High Resolution Electron Microscopy [HRTEM] and Electron Diffraction [ED]. In the current note we present direct evidence of charge-orbital ordering in this material using heat capacity measurements. Our heat capacity measurements indicate a clear transition consistent with prior observation. We find two main transitions, one at temperature T HC H = 310−314 K, and other in the vicinity of T HC A = 143 K. In addition, we may also conclude that there is a strong electron-phonon coupling in this material. In order to further study and confirm these anomalies we have performed dc magnetization measurements. The dc magnetic measurements confirm these two transitions. Again,we find two main transitions, one at temperature T M H = 318 − 323 K, and other at around T M A = 164 K. PACS numbers: 78.20.-e, 78.30.-j, 74.76.Bz 1 The transition-metal oxides display a wide variety of interesting properties. In particular of interest are the 3d transition metals such as Fe, Cu, Ni, Co and Mn, having a single layered perovskite structure, i.e. K 2 NiF 4 -type. These materials provide us useful insights into the underlying Mott-Hubbard in addition to helping us understand the superconducting oxides to which they are similar. In a recent note we [1] have shown the existence of inhomogenous charge distribution in very good quality single crystal of LaSrCuO 4 [LSCO] co-doped with 1% Zn at the copper site, using temperature dependent polarized X-ray absorption near-edge structure [XANES] spectra. A related single-layered compound to the LSCO is LaSrFeO 4 whose atomic and magnetic structure was first elucidated by Souberoux et al.[2], using X-ray diffraction, Mossbauer spectroscopy and neutron diffraction in polycrystalline state. Recently Kawanaka [3] have prepared a single crystal of LaSrFeO 4 by floating-zone method and demonstrated a spin flop transition in the antiferromagnetic ground state.In particular it seems that 3d-electron systems exhibit ordering and disordering of the fundamental degrees of freedom such as charge, spin and orbital. In turn it is plausible that this may be responsible for metal-insulator transition[3], high-T c superconductivity [1,4], and colossal magnetoresistance [5]. A class of materials which show charge-orbital ordering of e g electrons are the mixed valent manganites, the perovskite-type:where RE=trivalent lanthanides, and AE=divalent alkaline-earth ions. The real-space ordering pattern, possibly induced by strong electron-phonon interaction, that is a cooperative Jahn-Teller effect, can be determined by crystallographic superstructure [6,7]. What physical insight can be gained from these crystallographic superstructure? Here are some examples, for the case of the overdoped single-layered manganites, the suggested models [7,8] indicate that the Mn valence is not an integer but suffers a ...