Sequence-Controlled Copolymerization of Salicylic O-Carboxyanhydrides by Organocatalysts
Jinpeng Liang,
Jing Yang
Abstract:The composition sequence of a copolymer is intricately linked to its physical and mechanical properties. However, achieving chemical selectivity for copolymerization monomers and controlling the sequence structure of copolymers remain a challenge. This study delves into a strategy that involves tuning the organocatalyst transition from hydrogen bonding interaction to ionic pair to realize copolymerization sequence control in one-pot reactions. Ring-opening copolymerization (ROCOP) of salicylic acid O-carboxyan… Show more
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