Separation studies in a continuous flow fluorous biphasic system

Perperi, Evangelia; Huang, Yangen; Angeli, Panagiota; Manos, George; Cole‐Hamilton, David J.

doi:10.1016/j.molcata.2004.05.038

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Dimethyl-3-butyl-imidazolium) In [Bmim]bf 4 [Bmim]pf 6 Or2

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“…Efficient stirring was essential for high conversion and minimized alkene isomerization. The separation efficiency was found to be affected by the conversion and the partition of both the product in fluorous phase and the fluorous solvent in an organic phase, but not by the pressure [211].…”

Section: Dimethyl-3-butyl-imidazolium) In [Bmim]bf 4 [Bmim]pf 6 Ormentioning

confidence: 92%

See 1 more Smart Citation

Toward green catalytic synthesis—Transition metal-catalyzed reactions in non-conventional media

Liu

Xiao

2007

Journal of Molecular Catalysis A: Chemical

241

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Section: Dimethyl-3-butyl-imidazolium) In [Bmim]bf 4 [Bmim]pf 6 Ormentioning

confidence: 92%

“…A continuous flow fluorous biphasic system has been developed for hydroformylation of high olefins [210,211]. The system was tested on the hydroformylation of 1-octene, affording conversions up to 70% with n/iso ratio around 12 and successful fluorous catalyst recycling [210].…”

Section: Dimethyl-3-butyl-imidazolium) In [Bmim]bf 4 [Bmim]pf 6 Ormentioning

confidence: 99%