“…The increasing trend with the RH indicates that the solution-diffusion mechanism has a small contribution toward CO 2 transport through the membrane. Similar trends were observed by other workers which indicated that faster rate of diffusion was due to the formation of HCO3 -through this water-swollen FSC membrane, which eventually exhibits high CO 2 permeance and consequently high selectivity [2,66,70]. Some of the water in the flue gas stream will inevitably permeate with the CO 2 in these facilitated transport membranes.…”
Section: Effect Of Feed Gas Relative Humidity (Rh)supporting
confidence: 87%
“…PSf is considered to be one of the good support materials due to properties in terms of good thermal and mechanical stability, ease of manufacturing, reproducible properties and good gas transport properties. PSf has been successfully used in several studies for CO 2 capture in FSC membranes [2,63,67,68]. [65] a) b) Figure 3.…”
Section: Influence Of Selected Parameters On Fscs Performance 231 Ementioning
confidence: 99%
“…She has around 80 peer reviewed membrane articles in international highly recognized journals. Her group is currently testing facilitated transport membranes for CO 2 …”
Section: Conclusion and Summarymentioning
confidence: 99%
“…Membrane technology has been actively used for many years for CO 2 separation in natural gas sweetening as it offers several advantages over other techniques including its environmental friendliness, lower capital cost, lower energy consumption, better space utility, and better suitability for applications in remote locations [1][2][3]. In this regard, fabrication of efficient membranes is the most important parameter in determining the advantageous nature and efficiency of this technology compared to other separation techniques.…”
CO 2 emission from anthropogenic sources has raised global environmental concerns, and efficient reduction of these greenhouse gas emissions by capturing CO 2 is recognized world-wide as very important along with the implementation of new green energy technology. Membrane technology is considered to be one of the efficient techniques to be used for CO 2 capture. Among different types of membranes, mixed matrix membranes and facilitated transport membranes have gained much interest in recent years due to documented high CO 2 permeance through these membranes, especially when the gas is humid as is the case for flue gas from combustion. In the current review, a comprehensive discussion is focused on the development of hybrid membranes involving the selection of the fixed site carrier (FSC) membranes and the interaction of nanosilica-particles in a polymer membrane for efficient CO 2 capture. Other facilitated transport membranes and mixed matrix membranes are also briefly discussed.
“…The increasing trend with the RH indicates that the solution-diffusion mechanism has a small contribution toward CO 2 transport through the membrane. Similar trends were observed by other workers which indicated that faster rate of diffusion was due to the formation of HCO3 -through this water-swollen FSC membrane, which eventually exhibits high CO 2 permeance and consequently high selectivity [2,66,70]. Some of the water in the flue gas stream will inevitably permeate with the CO 2 in these facilitated transport membranes.…”
Section: Effect Of Feed Gas Relative Humidity (Rh)supporting
confidence: 87%
“…PSf is considered to be one of the good support materials due to properties in terms of good thermal and mechanical stability, ease of manufacturing, reproducible properties and good gas transport properties. PSf has been successfully used in several studies for CO 2 capture in FSC membranes [2,63,67,68]. [65] a) b) Figure 3.…”
Section: Influence Of Selected Parameters On Fscs Performance 231 Ementioning
confidence: 99%
“…She has around 80 peer reviewed membrane articles in international highly recognized journals. Her group is currently testing facilitated transport membranes for CO 2 …”
Section: Conclusion and Summarymentioning
confidence: 99%
“…Membrane technology has been actively used for many years for CO 2 separation in natural gas sweetening as it offers several advantages over other techniques including its environmental friendliness, lower capital cost, lower energy consumption, better space utility, and better suitability for applications in remote locations [1][2][3]. In this regard, fabrication of efficient membranes is the most important parameter in determining the advantageous nature and efficiency of this technology compared to other separation techniques.…”
CO 2 emission from anthropogenic sources has raised global environmental concerns, and efficient reduction of these greenhouse gas emissions by capturing CO 2 is recognized world-wide as very important along with the implementation of new green energy technology. Membrane technology is considered to be one of the efficient techniques to be used for CO 2 capture. Among different types of membranes, mixed matrix membranes and facilitated transport membranes have gained much interest in recent years due to documented high CO 2 permeance through these membranes, especially when the gas is humid as is the case for flue gas from combustion. In the current review, a comprehensive discussion is focused on the development of hybrid membranes involving the selection of the fixed site carrier (FSC) membranes and the interaction of nanosilica-particles in a polymer membrane for efficient CO 2 capture. Other facilitated transport membranes and mixed matrix membranes are also briefly discussed.
“…Unfortunately these membranes still have relatively thick separation layers and thus low permeance of about 1 m 3 (STP)/(m 2 h bar). It should be mentioned that when using advanced coating techniques and membrane preparation conditions permeance can reach about 10 m 3 (STP)/(m 2 h bar) [19]. If active transport membranes would be stable against the post-combustion feed stream such membranes would be very competitive candidates for industrial separation systems.…”
Abstract:Blend materials of Pebax ® 1657 and low molecular weight poly(ethylene glycol)s were studied for their stability at temperature up to 90°C. It was found that a threshold of molecular weight exists at which leaching out of the low molecular weight compound from the polymer matrix becomes minimal. Poly(ethylene glycol) with methyl end groups having a molecular weight of 500 g/mol provides a blend material with a CO 2 permeability coefficient higher than in case of Polyactive™. PEBAX ® /DM500 blend can be a cheaper alternative to tailor made Polyactive™ in large scale production of thin film composite membrane.
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