Separation of trivalent actinides and lanthanides from simulated high-level waste using cobalt bis(dicarbollide) ion derivate substituted with diphenyl-N-tert.octyl-carbamoylmethylphosphine oxide
Abstract:Dicarbollide / CMPO / Liquid-liquid extraction / Actinides / Lanthanides / High level liquid wasteSummary. A derivative with cobalt bis(dicarbollide)(1 − ) ion covalently bonded with diphenyl-N-tert.octyl-carbamoylmethylphosphine oxide with a formula [(8-Ph 2 P(O)-CH 2 C(O) Co] − (CMPO-COSAN) has been evaluated for actinides(III)/lanthanides(III) separation from high level liquid waste (HLLW) from PUREX reprocessing. The procedures for HLLW treatment by CMPO-COSAN dissolved in low polar mixture of hexylmethylk… Show more
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