“…29 Based on this, the absorptivity at 280 nm (ε280) is commonly used as an index of the degree of aromaticity of humic substances. 19,[24][25][26] The higher value of the original ε280 for HHA indicates that it contains a higher degree of aromatic structures than SHA and PHA, consistent with the features of pyrolysates (Fig. 5).…”
Section: Structural Features Of Has As Elucidated By Uv-vis Analysissupporting
To maintain performance related to fuel consumption and maneuverability, the bottom of ships are painted with antifouling paint that contains Cu2O as a biocidal pigment. However, in enclosed coastal areas around dockyards, some of the Cu(II) contained in the paint is eluted into the surrounding water. The present study examined the removal of Cu from seawater by co-precipitation with humic acids (HAs). After precipitating the HA in seawater, the amount of Cu(II) in the supernatant was colorimetrically measured by a colorimetry using bathocuproine. The removal efficiency (RE%) for micromolar Cu(II) increased with increasing initial concentrations of HAs. An RE of 90% was obtained using an HA derived from hardwood bark compost. Aromatic components in the HA that contained highly substituted acidic functional groups appeared to enhance the removal of Cu(II). The findings reported herein indicate that HAs represent a useful material for removing trace levels of Cu from seawater.
“…29 Based on this, the absorptivity at 280 nm (ε280) is commonly used as an index of the degree of aromaticity of humic substances. 19,[24][25][26] The higher value of the original ε280 for HHA indicates that it contains a higher degree of aromatic structures than SHA and PHA, consistent with the features of pyrolysates (Fig. 5).…”
Section: Structural Features Of Has As Elucidated By Uv-vis Analysissupporting
To maintain performance related to fuel consumption and maneuverability, the bottom of ships are painted with antifouling paint that contains Cu2O as a biocidal pigment. However, in enclosed coastal areas around dockyards, some of the Cu(II) contained in the paint is eluted into the surrounding water. The present study examined the removal of Cu from seawater by co-precipitation with humic acids (HAs). After precipitating the HA in seawater, the amount of Cu(II) in the supernatant was colorimetrically measured by a colorimetry using bathocuproine. The removal efficiency (RE%) for micromolar Cu(II) increased with increasing initial concentrations of HAs. An RE of 90% was obtained using an HA derived from hardwood bark compost. Aromatic components in the HA that contained highly substituted acidic functional groups appeared to enhance the removal of Cu(II). The findings reported herein indicate that HAs represent a useful material for removing trace levels of Cu from seawater.
“…In previous reports, surface tension of HA increased above pH 6, suggesting that HA became to be difficult to aggregate above pH 6 [31]. In addition, ion-pair formation between fulvic acid and alkylammonium surfactants is optimal at pH 7, and the higher pH resulted in the decrease of the formation [32]. These issues suggest that HA becomes to be difficult to coagulate in neutral to weak alkaline condition.…”
Section: Effect Of Ph On Coagulation Performancementioning
“…The extraction and purification of HA and FA were based on a method approved by the International Humic Substances Society [19,20]. The mixture of dry compost and 0.05 M aqueous NaOH (solid/liquid = 1:10, w/w) was shaken under a N 2 atmosphere for 24 h. Subsequently, the suspension was centrifuged at 10,397 × g for 15 min, and the supernatant was then filtered through an ADVANTEC 5A filter paper (collected particle size >0.7 m; ash content <0.01%).…”
Section: Extraction and Purification Of Ha And Famentioning
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