“…UV spectrophotometry amongst the optical methods seems to be the most appropriate analytical approach for the determination of toxic metals, as it provides sensitive, precise and accurate measurement of suitable analytes. Besides, visible spectrophotometric detection is much more viable as a useful technique to develop a portable, online or at‐line system . Many spectrophotometric methods can be found in the literature for mercury determination using complexing agents such as 4‐(2‐pyridylazo)‐resorcinol , 1,3‐di‐(4‐nitrodiazoamino)‐benzene , o ‐carboxy phenyl diazoamino p ‐asobenzene , potassium iodide , 2‐mercaptobenzothiazole (MBT) and 5‐(p‐aminobenzylidene)‐thaioyhiorhodamine .…”