Nickel
nitride (Ni3N) is a superior hydrogen evolution reaction
(HER) catalyst where the nitrogen source is usually ammonia and the
reaction temperature is high during the synthesis process. Herein,
we employed an innovative method to obtain three-dimensional porous
nickel nitride nanosheets on Ni foam (Ni3N/NF) by transforming
Ni(OH)2 nanosheets in N2–H2 glow discharge plasma. The obtained Ni3N/NF displays
a high HER activity with a small overpotential of 44 mV and a low
Tafel slope of 46 mV dec–1, which is competitive
to a Pt/C catalyst. Both the test data and simulation results prove
that active ions and radicals in plasma play essential roles in achieving
the facile nitridation, as well as building a nanostructured morphology
over the Ni3N/NF surface. The unique synthesis method opens
new avenues for metal nitrides of HER catalysts and beyond.