Core–shell microgels are of increasing interest as smart carriers of catalysts, as sensors, or as building blocks for colloidal superstructures. In the context of colloidal assemblies, photonic applications are probably the most promising ones. This progress report presents and discusses the most recent results in this area focusing on the last 2–3 years, and also gives some background information. In addition, potential perspectives of this area will be outlined. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2013, 51, 1073–1083