Abstract:The development of heterogeneous chiral dirhodium catalysts for fabricating important bioactive substances and reducing the loss of noble metals has long been of significant interest. However, there still remains formidable synthetic challenges since it requires multiple steps of the synthetic process, and rhodium is easily leached from solid materials during the reaction. Here, we demonstrated a self-supported strategy based on the Suzuki−Miyaura coupling reaction to construct two chiral dirhodium organic fra… Show more
Herein, we report the use of a molecular-defined rhodium(ii) coordination polymer (Rh-CP) as a heterogeneous, recyclable catalyst in carbene transfer reactions.
Herein, we report the use of a molecular-defined rhodium(ii) coordination polymer (Rh-CP) as a heterogeneous, recyclable catalyst in carbene transfer reactions.
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