Tntroduction ofpolymers into the cement composites improves same of the properties of concretes and mortars.Therefore, the polymer-cement composites are successfully used in construction. The model of microstructure formation in cement composites modified with thermoplastic polymer (pre-mix modifiers) has already been developed and successfully implemented. However, the formation ofmicrostructure in the case of epoxy-cement composites ( containing post-mix modifier) demonstrates same peculiarities wbich shou]d be taken into account when modelling the process. The microstructure of epoxy-cement composites and its formation is discussed in the paper. The model is offered, formulated on the basis of the microscopic observations and results oftesting.