“…Though it was an ideal two dimensional material of theoretical interest and one of the earliest material on which tight binding band structure calculation was done 2,3 , it has triggered recently a lot of interest among people including reinvestigation of many earlier results since its experimental discovery in 2004 4 . Particularly, a large no of people have recalculated the tight binding band with nearest neighbour hopping but without overlap integral correction 1,2,3,5,6,7,8,9 , some have calculated the same by taking into account the overlap integral correction 2,8 , out of these only few calculations are there which take care of second and third nearest neighbours along with overlap integral corrections 1,9 . It is noticed that the first nearest neighbour hopping integral (γ 0 ) lies around 2.5eV-3.0eV when tight binding band is fitted with first principle calculation or experimental data 1,6,8 near the K point of the brillouin zone of graphene but interestingly, when one tries to have a good matching of the tight binding band over the whole brillouin zone by including upto third nearest neighbour hoppings and overlap integrals, the tight binding parameters are considered as merely fitting parameters, not as physical entities 1 i.e, the values of parameters do not decrease consistently as one moves towards second and third nearest neighbours.…”