Self‐Assembly of Discrete Oligomers of Naphthalenediimides in Bulk and on Surfaces
Christiaan H. W. A. Corbet,
Bart W. L. van den Bersselaar,
Bas F. M. de Waal
et al.
Abstract:Here, we report on the synthesis of discrete oligomers of alkyl‐bridged naphthalenediimides (NDIs) and study their molecular nanostructures both in bulk, in solution, and at the liquid‐solid interface. Via an iterative synthesis method, multiple NDI cores were bridged with short and saturated alkyl‐diamines (C3 and C12) or long and unsaturated alkyl‐diamines (u2C33 to u8C100) at their imide termini. The strong intermolecular interaction between the NDI cores was observed by probing their photophysical properti… Show more
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