Self-assembly of discrete metallosupramolecular luminophores

Cooke, Michael W.; Chartrand, Daniel; Hanan, Garry S.

doi:10.1016/j.ccr.2008.01.006

Cited by 91 publications

(21 citation statements)

References 155 publications

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“…Thus, complex T1 has been successfully detected at m/z = 375.00299, making possible its formulation as [T1 − CF 3 …”

Section: Synthesis and Spectroscopic Studiesmentioning

confidence: 99%

“…Organometallic complexes play a major role in many fields of chemistry, as precursors to new materials [1][2][3], in catalysis [4,5] and in applications to medicine [6,7]. Their versatility is associated with the possibility of finely tuning the stereoelectronic properties of metal centers by changing ligands, oxidation state and electronic configuration.…”

Section: Introductionmentioning

confidence: 99%

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Mo(II) complexes: A new family of cytotoxic agents?

Bandarra

Lopes

et al. 2010

Journal of Inorganic Biochemistry

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“…Thus, complex T1 has been successfully detected at m/z = 375.00299, making possible its formulation as [T1 − CF 3 …”

Section: Synthesis and Spectroscopic Studiesmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Mo(II) complexes: A new family of cytotoxic agents?

Bandarra

Lopes

et al. 2010

Journal of Inorganic Biochemistry

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“…In aqueous solution, octahedral complexes of the type [M (1,10- with first-row transition metal cations can be expected [3,4]. The strong and predictable binding of 1,10-phen has led to its use as an auxiliary ligand in the design of metal-organic frameworks [5].…”

Section: Introductionmentioning

confidence: 99%

[Ni(1,10-phenanthroline)2(H2O)2](NO3)2: A Simple Coordination Complex with a Remarkably Complicated Structure that Simplifies on Heating

2011

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Despite the simple chemical formula, [Ni(1, cations and twelve nitrate anions. Detailed analyses of the crystal structure and O-H⋅⋅⋅O and C-H⋅⋅⋅O hydrogen bonding interactions are reported and discussed. In this way the anion-directed assembly of the 3-D structure is illustrated. The thermal and spectroscopic properties of the compound are described. Upon heating to 308 K, the crystal undergoes a phase change to a much simpler structure with a single [Ni(1, cation within the asymmetric unit and unit cell volume one sixth of that at low temperature. Although the crystal decomposed during data collection, it was possible to establish the molecular packing in the high temperature form and relate it to that at low temperature.

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“…The residue was chromatographed on Al 2 O 3 (gradient elution with C 6 H 6 -MeCN from 10 : 1 to 4 : 1). This procedure was used to obtain 2 [2 (2,3,5,6,8,9,11,12,14,15 decahydrobenzo [1,7,10,16,4,13]tetraoxadithiacyclooctadecin 18 yl)ethenyl] 9 methyl 1,10 phenanthroline (3a), 2 {2 [4 (1,4 dioxa 7,13 dithia 10 azacyclopentadecan 10 yl)phenyl]ethenyl} 9 methyl 1,10 phenanthroline (3c), and 2,9 bis{2 [4 (1,4 dioxa 7,13 dithia 10 azacyclopentadecan 10 yl)phenyl]ethenyl} 1,10 phenanthroline (4c). For the yields of the products, see Table 1.…”

Section: Methodsmentioning

confidence: 99%